Electrodialysis Process Application for Pigment Wastewater Treatment Using Ion Exchange Membranes
Abstract
Electrodialysis (ED) is an efficient technique for treating high-salinity industrial effluents. This study examined the removal efficiencies of sodium chloride (NaCl), sodium acetate (C2H3NaO2), and acetic acid (CH3COOH) using electrodialysis. The procedure utilized a cation exchange membrane type MK-40 and an anion exchange membrane type MA-40. The impact of operational parameters, including electrolysis time, initial concentration, and applied current, was examined. The findings indicated that the removal efficiency improved over time, reaching 70% for NaCl at an initial concentration of 0.086 M and an applied current of 1 A. The elimination efficiency of C2H3NaO2 attained a maximum value of 97% at a concentration of 0.036 M and an applied current of 1 A. The maximum removal efficiency of acetic acid was 71%, achieved at a starting concentration of 0.033 M with an applied current of 1 A. The findings indicated that the current efficiency peaked at elevated initial concentrations of all examined contaminants, whereas increasing the applied current significantly enhanced removal efficiency. Consequently, electrodialysis is an efficient technique for removing certain contaminants from industrial effluents.
References
Abdelkader, S., 2023. “Assessment of water quality of house water using water pollution index in Mosul City.” NTU J Pure Sci., 2(4), 9-16.
Ahmed, A.E., Grzegorzek, M., Majewska-Nowak, K., 2019. “The effect of nitrate on fluoride removal by batch electrodialysis.” Environ. Prot. Eng., 45(4), 87–101.
Ahmed, S.F., Mehejabin, F., Momtahin, A., Tasannum, N., Faria, N.T., Mofijur, M., Hoang, A.T., Vo, D.V.N., Mahlia, T.M.I., 2022. “Strategies to improve membrane performance in wastewater treatment.” Chemosphere, 306, 135527. https://doi.org/10.1016/j.chemosphere.2022.135527
Aziz, N. A., Salih, S. M., & Hama-Salh, N. Y., 2012. “Pollution of Tanjero river by some heavy metals generated from sewage wastwater and industrial wastewater in Sulaimani district.” Kirkuk J. Sci., 7(1), 67-84. https://doi.org/10.32894/kujss.2012.44614
Banasiak, L.J., Kruttschnitt, T.W., Schäfer, A.I., 2007. “Desalination using electrodialysis as a function of voltage and salt concentration.” Desalination, 205(1-3), 38-46. https://doi.org/10.1016/j.desal.2006.04.038
Caprarescu, S., Miron, A.R., Purcar, V., Radu, A.L., Sarbu, A., Ion-Ebrasu, D., Atanase, L.I., Ghiurea, M., 2016. “Efficient removal of Indigo Carmine dye by a separation process.” Water Sci. Technol., 74(10), 2462-2473. https://doi.org/10.2166/wst.2016.388
Crini, G., Lichtfouse, E., 2019. “Advantages and disadvantages of techniques used for wastewater treatment.” Environ. Chem. Lett., 17,.145-155. https://doi.org/10.1007/s10311-018-0785-9
Du, H., Xie, L., Liu, J., Xu, S., 2021. “Concentration of mixed acid by electrodialysis for the intensification of absorption process in acrylic acid production.” Chin. J. Chem. Eng., 36, 10-18. https://doi.org/10.1016/j.cjche.2020.07.020
Gao, E., Meng, R., Jin, Q., Yao, S., Wu, Z., Li, J., Du, E., 2023. “Highly effective mineralization of acetic acid wastewater via catalytic ozonation over the promising MnO2/γ-Al2O3 catalyst.” Chem. Phys. Impact, 6, 100149. https://doi.org/10.1016/j.chphi.2022.100149
Gherasim, C.V., Křivčík, J., Mikulášek, P., 2014. “Investigation of batch electrodialysis process for removal of lead ions from aqueous solutions.” Chem. Eng. J., 256, 324-334. https://doi.org/10.1016/j.cej.2014.06.094
Gubari, M.Q., Zwain, H.M., Al-Zahiwat, M.M. Alekseeva, N.V., 2021. “Characteristics of the MK-40 and MA-40 membranes for industrial wastewater treatment–A Review.” Ecol. Eng. Environ. Technol., 22, 39–50. https://doi.org/10.12912/27197050/132095
Gurreri, L., Tamburini, A., Cipollina, A., Micale, G., 2020. “Electrodialysis applications in wastewater treatment for environmental protection and resources recovery: A systematic review on progress and perspectives.” Membranes, 10(7), 146. https://doi.org/10.3390/membranes10070146
Han, L., Galier, S., Roux-de Balmann, H., 2017. “A phenomenological model to evaluate the performances of electrodialysis for the desalination of saline water containing organic solutes.” Desalination, 422, 17-24. https://doi.org/10.1016/j.desal.2017.08.008
Jaroszek, H., Dydo, P., 2016. “Ion-exchange membranes in chemical synthesis–a review.” Open Chem., 14(1), 1-19. https://doi.org/10.1515/chem-2016-0002
Kim, Y., Logan, B.E. 2013. Simultaneous removal of organic matter and salt ions from saline wastewater in bioelectrochemical systems. Desalination, 308, 115-121. https://doi.org/10.1016/j.desal.2012.07.031
Kwak, R., Guan, G., Peng, W.K., Han, J., 2013. “Microscale electrodialysis: Concentration profiling and vortex visualization.” Desalination, 308, 138-146. https://doi.org/10.1016/j.desal.2012.07.017
Lee, J.W., Trinh, L.T.P., Lee, H.J., 2014. “Removal of inhibitors from a hydrolysate of lignocellulosic biomass using electrodialysis.” Sep. Purif. Technol., 122, 242-247. https://doi.org/10.1016/j.seppur.2013.11.008
Maciej, A., Łatanik, N., Sowa, M., Matuła, I., Simka, W., 2021. “Electrodeposition of copper and brass coatings with olive-like structure.” Materials, 14(7), 1762. https://doi.org/10.3390/ma14071762
Malek, P., Ortiz, J.M., Richards, B.S., Schaefer, A.I., 2013. “Electrodialytic removal of NaCl from water: Impacts of using pulsed electric potential on ion transport and water dissociation phenomena.” Science. Membr. Sci., 435, 99-109. https://doi.org/10.1016/j.memsci.2013.01.060
Masigol, M.A., Moheb, A., Mehrabani-Zeinabad, A., 2012. “An experimental investigation into batch electrodialysis process for removal of sodium sulfate from magnesium stearate aqueous slurry.” Desalination, 300, 12-18. https://doi.org/10.1016/j.desal.2012.05.025
Melnikov, S.S., Nosova, E.N., Melnikova, E.D., Zabolotsky, V.I., 2021. “Reactive separation of inorganic and organic ions in electrodialysis with bilayer membranes.” Sep. Purif. Technol., 268, 1–14. https://doi.org/10.1016/j.seppur.2021.118561
Mendoza, R.M.O., Dalida, M.L.P., Kan, C.C., Wan, M.W., 2018. “Groundwater treatment by electrodialysis: Gearing up towards green technology.” Desalin. Water Treat., 127, 178-183. https://doi.org/10.5004/dwt.2018.22929
Obotey Ezugbe, E., Rathilal, S., 2020. “Membrane technologies in wastewater treatment: a review.” Membranes, 10(5), 89. https://doi.org/10.3390/membranes10050089
Othman, M. A., 2023. "Investigation removal efficiency of electrocoagulation process as a slaughterhouse wastewater treatment technique: toxicity assessment.” Kirkuk J. Sci., 18(4), 1-9. https://doi.org/10.32894/kujss.2023.142319.1111
Oztekin, E., Altin, S., 2016. “Wastewater treatment by electrodialysis system and fouling problems.” J. Sci. Technol., 6, 91–99.
Patil, R., Truong, C., Genco, J.O.S.E.P.H., Pendse, H.E.M.A.N.T., Van Heiningen, A.D.R.I.A.A.N., 2015. “Applicability of electrodialysis to the separation of sodium acetate from synthetic alkaline hardwood extract.” Tappi J., 14, 695-708. https://doi.org/10.32964/TJ14.11.695
Rukowicz, B., 2023. “Electrodeionization for the Bio-Succinic Acid Production Process.” ACS Sustain. Chem. Eng., 11(31), 11459-11469. https://doi.org/10.1021/acssuschemeng.3c01285
Samarghandi, M.R., Dargahi, A., Shabanloo, A., Nasab, H.Z., Vaziri, Y., Ansari, A., 2020. “Electrochemical degradation of methylene blue dye using a graphite doped PbO2 anode: optimization of operational parameters, degradation pathway and improving the biodegradability of textile wastewater.” Arab. J. Chem., 13(8), 6847-6864. https://doi.org/10.1016/j.arabjc.2020.06.038
Sarapulova, V., Shkorkina, I., Mareev, S., Pismenskaya, N., Kononenko, N., Larchet, C., Dammak, L.N., V., 2019. “Transport characteristics of fujifilm ion-exchange membranes as compared to homogeneous membranes АМХ and СМХ and to heterogeneous membranes MK-40 and MA-41.” Membranes, 9(7), 1-23. https://doi.org/10.3390/membranes9070084
Silva, V., Poiesz, E., van der Heijden, P., 2013. “Industrial wastewater desalination using electrodialysis: evaluation and plant design.” J. Appl. Electrochem., 43(11), 1057-1067. https://doi.org/10.1007/s10800-013-0551-4
Sriram, G., Uthappa, U.T., Kigga, M., Jung, H.Y., Altalhi, T., Brahmkhatri, V., Kurkuri, M.D., 2019. “Xerogel activated diatoms as an effective hybrid adsorbent for the efficient removal of malachite green.” New J. Chem., 43(9), 3810-3820. https://doi.org/10.1039/C9NJ00015A
Suwal, S., Li, J., Engelberth, A.S., Huang, J.Y., 2018. “Application of electro-membrane separation for recovery of acetic acid in lignocellulosic bioethanol production.” Food Bioprod. Process., 109, 41-51. https://doi.org/10.1016/j.fbp.2018.02.010
Talebi, S., Chen, G.Q., Freeman, B., Suarez, F., Freckleton, A., Bathurst, K., Kentish, S.E., 2019. “Fouling and in-situ cleaning of ion-exchange membranes during the electrodialysis of fresh acid and sweet whey.” J. Food Eng., 246, 192-199. https://doi.org/10.1016/j.jfoodeng.2018.11.010
Xue, S., Wu, C., Wu, Y., Zhang, C., 2018. “An optimized process for treating sodium acetate waste residue: Coupling of diffusion dialysis or electrodialysis with bipolar membrane electrodialysis.” Chem Eng. Res. Des., 129, 237-247. https://doi.org/10.1016/j.cherd.2017.11.013
Yu, L., Guo, Q., Hao, J., Jiang, W., 2000. “Recovery of acetic acid from dilute wastewater by means of bipolar membrane electrodialysis.” Desalination, 129(3), 283-288. https://doi.org/10.1016/S0011-9164(00)00068-0
Zhang, X., Li, C., Wang, Y., Luo, J., Xu, T., 2011. “Recovery of acetic acid from simulated acetaldehyde wastewaters: Bipolar membrane electrodialysis processes and membrane selection.” J. Membr. Sci., 379(1-2), 184-190. https://doi.org/10.1016/j.memsci.2011.05.059
Copyright (c) 2026 ASEAN Journal of Chemical Engineering

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright holder for articles is ASEAN Journal of Chemical Engineering. Articles published in ASEAN J. Chem. Eng. are distributed under a Creative Commons Attribution-NonCommercial 4.0 International (CC BY-NC 4.0) license.
Authors agree to transfer all copyright rights in and to the above work to the ASEAN Journal of Chemical Engineering Editorial Board so that the Editorial Board shall have the right to publish the work for non-profit use in any media or form. In return, authors retain: (1) all proprietary rights other than copyright; (2) re-use of all or part of the above paper in their other work; (3) right to reproduce or authorize others to reproduce the above paper for authors’ personal use or for company use if the source and the journal copyright notice is indicated, and if the reproduction is not made for the purpose of sale.