The Tear and Tensile Strengths of Silica Fly Ash Reinforced Natural Rubber Vulcanizate
Abstract
This study investigated the enhancement of tear and tensile strengths in natural rubber (NR) vulcanizates reinforced with silica fly ash. The focus was on evaluating the tear and tensile strengths of the composites to improve their performance across various industrial applications. NR, known for its elasticity and flexibility, is often reinforced with fillers to enhance its mechanical properties. Silica fly ash, a by-product of coal combustion, was utilized as a reinforcing agent due to its high silica content and fine particle size. A series of NR composites was prepared by incorporating silica fly ash at weight percentages ranging from 10 to 40 parts per hundred parts of NR (phr). The vulcanization process was optimized to ensure uniform dispersion of the fly ash particles within the NR matrix. The resulting vulcanizates were then subjected to standardized testing to measure their tear and tensile strengths. Results indicated a significant improvement in both tear and tensile strengths with the addition of silica fly ash, particularly at an optimal filler loading. The tear and tensile strengths of the NR vulcanizate with 30 phr silica fly ash (optimal filler loading) were 84.3 N/mm and 29.0 MPa, which were much higher than those of the tear and tensile strengths of the NR vulcanizate with no silica fly ash; 41.2 N/mm and 19.0 MPa, respectively. The 100% modulus, maximum, and delta torque for NR/silica fly ash vulcanizate were higher than those of unfilled NR vulcanizate. The study concludes that silica fly ash is a viable, cost-effective filler for NR, offering substantial improvements in mechanical properties. This finding not only promotes the use of industrial waste but also opens avenues for developing high-performance rubber composites for diverse applications.
References
Abdelsalam, A. A., S. Araby, S. H. El-Sabbagh, A. Abdelmoneim and M. A. Hassan., 2019. "Effect of carbon black loading on mechanical and rheological properties of natural rubber/styrene-butadiene rubber/nitrile butadiene rubber blends." J. Thermoplastic Compos. Mater. 34(4), 490-507. https://doi.org/10.1177/0892705719844556
Ansarifar, A., S. F. Shiah and M. Bennett., 2006. "Optimising the chemical bonding between silanised silica nanofiller and natural rubber and assessing its effects on the properties of the rubber." Int. J. Adhes. Adhes. 26, 454-463. https://doi.org/10.1016/j.ijadhadh.2005.06.008
Barlow, F. W., 2018. Rubber compounding: principles, materials, and techniques, CRC Press.
Bernal-Ortega, P., R. Anyszka, Y. Morishita, R. di Ronza and A. Blume., 2024. "Determination of the crosslink density of silica-filled styrene butadiene rubber compounds by different analytical methods." Polym. Bullet. 81(1), 995-1018. https://doi.org/10.1007/s00289-023-04749-x
Bhowmick, A. K. and H. L. Stephens., 2001. Handbook of elastomers. Boca Raton, Florida, CRC Press.
Bokobza, L., 2023. "Elastomer Nanocomposites: Effect of Filler–Matrix and Filler–Filler Interactions." Polymers 15(13), 2900. https://doi.org/10.3390/polym15132900
Chu, Q., X. Tian, H. Bian and C. Wang., 2025. "Optimization of mechanical and dynamic properties of tread rubber using fumed silica and hydration processing." Polymers 17(6), 714. https://doi.org/10.3390/polym17060714
Dileep, P. and S. K. Narayanankutty., 2020. "A novel method for preparation of nanosilica from bamboo leaves and its green modification as a multi-functional additive in styrene butadiene rubber." Mater Today Commun. 24, 100957. https://doi.org/10.1016/j.mtcomm.2020.100957
Gao, X., W. Yang, C. Wang and X. Tian., 2022. "Study on properties of carbon-coated silica prepared by polymer pyrolysis reinforced rubber composites." Polym. Test. 110, 107583. https://doi.org/10.1016/j.polymertesting.2022.107583
Hayeemasae, N., S. Soontaranon and A. Masa., 2024. "Comparative investigation of nano-sized silica and micrometer-sized calcium carbonate on structure and properties of natural rubber composites." Polymers 16(8), 1051. https://doi.org/10.3390/polym16081051
He, J., B. Huang, L. Wang, Z. Cai, J. Zhang and J. Feng., 2023. "Enhancing natural rubber tearing strength by mixing ultra-high molecular weight polyethylene short fibers." Polymers (Basel), 15(7). https://doi.org/10.3390/polym15071768
Ikeda, Y., 2014. 4 - Understanding network control by vulcanization for sulfur cross-linked natural rubber (NR). Chemistry, Manufacture and Applications of Natural Rubber. S. Kohjiya and Y. Ikeda, Woodhead Publishing, pp. 119-134.
Imoisili, P. E. and T.-C. Jen., 2024. "Synthesis and characterization of amorphous nano silica from South African coal fly ash." Mater. Today: Proceeding 105, 21-26. https://doi.org/10.1016/j.matpr.2023.06.077
Ismail, H. and H. Chia., 1998. "The effects of multifunctional additive and epoxidation in silica filled natural rubber compounds." Polym. Test. 17(3), 199-210. https://doi.org/10.1016/S0142-9418(97)00043-3
Ismail, H. and M. Mathialagan., 2012. "Comparative study on the effect of partial replacement of silica or calcium carbonate by bentonite on the properties of EPDM composites." Polym. Test. 31(2),199-208. https://doi.org/10.1016/j.polymertesting.2011.09.002
Ismail, H. and M. Mathialagan., 2013. "Compatibilization of bentonite filled ethylene-propylene-diene monomer composites: Effect of maleic anhydride grafted EPDM." J. Appl. Polym. Sci. 127(2), 1164-1171. https://doi.org/10.1002/app.37606
Ju, T., Y. Meng, S. Han, F. Meng, L. Lin, J. Li, Y. Du, M. Song, T. Lan and J. Jiang., 2023. "A green and multi-win strategy for coal fly ash disposal by CO2 fixation and mesoporous silica synthesis." Sci. Total Environ. 883, 163822. https://doi.org/10.1016/j.scitotenv.2023.163822
Kobędza, P., A. Smejda-Krzewicka and K. Strzelec., 2022. "Cross-link density, mechanical and thermal properties of chloroprene rubber cross-linked with silver(I) oxide." Materials, 15(6), 2006. https://doi.org/10.3390/ma15062006
Lei, Z., W. Hengliang, L. Zhang, J. Yang, L. Jianwei and W. Jingli., 2024. "A study on preparation and properties of fly ash-based SiO2 aerogel material." Colloids Surf. A: Physicochem. Eng. Asp. 684: 133016. https://doi.org/10.1016/j.colsurfa.2023.133016
Maciejewska, M. and A. Sowińska., 2021. "Influence of fillers and ionic liquids on the crosslinking and performance of natural rubber biocomposites." Polymers 13(10), 1656. https://doi.org/10.3390/polym13101656
Neethirajan, J., A. R. Parathodika, G.-H. Hu and K. Naskar., 2022. "Functional rubber composites based on silica-silane reinforcement for green tire application: the state of the art." Funct. Compos. Mater. 3(1), 7. https://doi.org/10.1186/s42252-022-00035-7
Pianese, G., G. Milani and F. Milani., 2024. "Kinetic mathematical model with induction and reversion for the vulcanization of natural rubber and ethylene propylene diene monomer blend." Polym. Test. 131, 108339. https://doi.org/10.1016/j.polymertesting.2024.108339
Robertson, C. G. and N. J. Hardman., 2021. "Nature of carbon black reinforcement of rubber: perspective on the original polymer nanocomposite." Polymers, 13(4), 538. https://doi.org/10.3390/polym13040538
Rodgers, B., 2015. Rubber compounding: chemistry and applications. CRC Press.
Rong, J., J. Yang, Y. Huang, W. Luo and X. Hu., 2021. "Characteristic tearing energy and fatigue crack propagation of filled natural rubber." Polymers 13(22), 3891. https://doi.org/10.3390/polym13223891
Sahakaro, K., C. Hayichelaeh, L. Reuvekamp, W. Dierkes, A. Blume and J. Noordermeer., 2019. “Bio-based Rubber Process Oils for Low Rolling Resistance Silica-Reinforced Natural Rubber Tire Tread Compounds.” International Conference on Innovation in Polymer Science and Technology, IPST 2019.
Saramolee, P., N. Lopattananon and K. Sahakaro., 2014. "Preparation and some properties of modified natural rubber bearing grafted poly(methyl methacrylate) and epoxide groups." Eur. Polym. J. 56, 1-10. https://doi.org/10.1016/j.eurpolymj.2014.04.008
Sethulekshmi, A., J. S. Jayan, A. Saritha and K. Joseph., 2022. "Recent developments in natural rubber nanocomposites containing graphene derivatives and its hybrids." Ind. Crops. Prod. 177, 114529. https://doi.org/10.1016/j.indcrop.2022.114529
Shojaei, M., G. Pircheraghi and M. Imani., 2024. "Application of modified, recycled nanosilica from battery wastes: A sustainable approach to enhance mechanical and aging properties of rubber nanocomposites." Polym. Test. 130, 108314. https://doi.org/10.1016/j.polymertesting.2023.108314
Smith, B. C., 2018. Infrared spectral interpretation: a systematic approach. CRC press.
Song, S. H., 2021. "Study on silica-based rubber composites with epoxidized natural rubber and solution styrene butadiene rubber." Polym. Polym. Compos. 29(9), 1422-1429. https://doi.org/10.1177/0967391120971391
Surya, I., 2021. “The utilization of aminopropyltriethoxy silane as a rubber additive in improving the degree of filler dispersion of natural rubber/precipitated silica composites.” IOP Conf. Ser.: Earth Environ. Sci. 782, 022066. https://doi.org/10.1088/1755-1315/782/2/022066
Surya, I., H. Ismail and J. Anto., 2024. “Processing and Tensile Properties of Natural Rubber Filled with Calcium Carbonate or Silica in the Presences of Lauryl Alcohol.” BIO Web of Conferences, EDP Sciences. https://doi.org/10.1051/bioconf/20249403002
Surya, I., A. Sembiring, K. Nasution and N. Hayeemasae., 2024. “The porosity and morphology properties of ceramic membrane.” J. Phys.: Conf. Ser. 2733, 012014. https://doi.org/10.1088/1742-6596/2733/1/012014
Surya, I., B. Siregar, M. Khatami and H. A. Khalil., 2024. “Fatty alcohols as sustainable compatibilizer agents for the compound of natural rubber/silica: The curing, rubberiness and tensile strength behaviours.” IOP Conf. Ser.: Earth Environ. Sci. 1352, 012030. https://doi.org/10.1088/1755-1315/1352/1/012030
Surya, I., K. Waesateh, S. Saiwari, H. Ismail, N. Othman and N. Hayeemasae., 2021. "Potency of urea-treated halloysite nanotubes for the simultaneous boosting of mechanical properties and crystallization of epoxidized natural rubber composites." Polymers 13(18), 3068. https://doi.org/10.3390/polym13183068
Thongsang, S., W. Vorakhan, E. Wimolmala and N. Sombatsompop., 2012. "Dynamic mechanical analysis and tribological properties of NR vulcanizates with fly ash/precipitated silica hybrid filler." Tribol. Int. 53, 134-141. https://doi.org/10.1016/j.triboint.2012.04.006
Um, G.-Y., T. Kwon, S. H. Lee, W. Kim, J. Kim, S. Yu, K. Kim and J. H. Lee., 2023. "Effect of functionality and loading procedure of liquid butadiene rubber on properties of silica-filled tire tread compounds." Polym. Test. 129, 108283. https://doi.org/10.1016/j.polymertesting.2023.108283
Utama, P. S., S. Bahri, B. A. Prawiranegara, D. Heltina and E. Saputra., 2022. "Synthesis of synthetic amorphous silica powder from palm oil mill fly ash extract by carbon dioxide impregnation." Materials Today: Proceedings 63, S297-S300. https://doi.org/10.1016/j.matpr.2022.03.143
Wang, L., Y. Shang and C. Li., 2023. "How to improve the initiative and effectiveness of enterprises to implement environmental management system certification?" J. Clean. Prod. 404, 137013. https://doi.org/10.1016/j.jclepro.2023.137013
Xing, L., X. Li, P. Cao, J. Luo and H. Jiang., 2024. "Stepwise extraction and utilization of silica and alumina from coal fly ash by mild hydrothermal process." Process Saf. Environ. Prot. 182, 918-929. https://doi.org/10.1016/j.psep.2023.12.035
Yan, H., G. Tian, K. Sun, Y. Zhang and Y. Zhang., 2005. "Effect of silane coupling agent on the polymer-filler interaction and mechanical properties of silica-filled NR." J. Poly,. Sci. B: Polym. Phys. 43(5), 573-584. https://doi.org/10.1002/polb.20343
Yang, H., L. Yang, H. Guo, W. Hu and A. Du., 2021. "The effect of silica modified by deep eutectic solvents on the properties of nature rubber/silica composites." J. Elastomer Plast. 54(1), 111-122. https://doi.org/10.1177/00952443211020051
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