Sequential Condensation and Hydrodeoxygenation Reaction of Furfural-Acetone Adduct over Mix Catalysts Ni/SiO2 and Cu/SiO2 in Water
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| 1. | Title | Title of document | Sequential Condensation and Hydrodeoxygenation Reaction of Furfural-Acetone Adduct over Mix Catalysts Ni/SiO2 and Cu/SiO2 in Water |
| 2. | Creator | Author's name, affiliation, country | Siti Mariyah Ulfa; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University, Jl. Veteran, Malang 65145, Indonesia; Indonesia |
| 2. | Creator | Author's name, affiliation, country | Rizka Fauzia Ohorella; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University, Jl. Veteran, Malang 65145, Indonesia; Indonesia |
| 2. | Creator | Author's name, affiliation, country | Caterina Widya Astutik; Department of Chemistry, Faculty of Mathematics and Natural Sciences, Brawijaya University, Jl. Veteran, Malang 65145, Indonesia; Indonesia |
| 3. | Subject | Discipline(s) | |
| 3. | Subject | Keyword(s) | hydrodeoxygenation; furfural; condensation; catalyst; liquid phase |
| 4. | Description | Abstract | Sequential condensation and hydrodeoxygenation reaction were perform using autoclave batch reactor in the presence of water as a solvent. The condensation of furfural and acetone was performed using MgO catalyst followed by hydrodeoxygenation using mix catalyst Ni/SiO2 and Cu/SiO2. The catalyst was prepared by wet-impregnation method and analyzed by XRD, SEM-EDX as well as BET surface. Condensation of furfural and acetone in 1:2 mol ratio was carried out by reflux gave 4-(2-furyl)-3-buten-2-one and 1,5-bis-(2-furanyl)-1,4-pentadien-3-one. The condensation product was then subjected for hydrodeoxygenation using batch reactor, catalyzed by mixed Ni/SiO2 and Cu/SiO2 at 150 and 180 °C for 2 h. The product identified as alkane derivatives with the conversion at 38.83 and 50.35%, respectively. The selectivity of hydrocarbon is 61.39% at 150 °C and 16.55% at 180 °C. Increasing the reaction temperature to 200 °C did not give any products except the recovery of the precursor. It showed that higher temperature enhanced the catalyst activity but the selectivity is controlled by low reaction temperature. |
| 5. | Publisher | Organizing agency, location | Universitas Gadjah Mada |
| 6. | Contributor | Sponsor(s) | This work was supported financially by the PUPT research grant from KEMENRISTEKDIKTI no: 063/SP2H/LT/DPRM/IV/2017 |
| 7. | Date | (YYYY-MM-DD) | 2017-12-28 |
| 8. | Type | Status & genre | Peer-reviewed Article |
| 8. | Type | Type | |
| 9. | Format | File format | Full Text PDF |
| 10. | Identifier | Uniform Resource Identifier | https://jurnal.ugm.ac.id/ijc/article/view/26736 |
| 10. | Identifier | Digital Object Identifier (DOI) | https://doi.org/10.22146/ijc.26736 |
| 11. | Source | Title; vol., no. (year) | Indonesian Journal of Chemistry; Article in press |
| 12. | Language | English=en | en |
| 13. | Relation | Supp. Files | |
| 14. | Coverage | Geo-spatial location, chronological period, research sample (gender, age, etc.) | |
| 15. | Rights | Copyright and permissions |
Copyright (c) 2017 Indonesian Journal of Chemistry This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License. |