Adsorption of Malachite Green and Methyl Violet 2B with Phthalate-Functionalized Sugarcane Bagasse

Dwi Ariani(1*), Nurul Hidayat Aprilita(2), Agus Kuncaka(3)

(1) Departement of Chemistry, Faculty of Mathematics and Natural Science, Universitas Gadjah Mada
(2) Departement of Chemistry, Faculty of Mathematics and Natural Science, Universitas Gadjah Mada
(3) Departement of Chemistry, Faculty of Mathematics and Natural Science, Universitas Gadjah Mada
(*) Corresponding Author


In this study, the adsorption of malachite green and methyl violet 2B by phthalate-functionalized sugarcane bagasse (SPA) was investigated. The chemical modification of sugarcane bagasse (SB) with PA using pyridine as a solvent and the SPA was optimized through the evaluation of the effects of mass ratio of SB-PA and reaction time of reflux on the value of carboxylic acid groups amount on SPA surface. The amount of carboxylic acid groups amount on SPA surface was determined by back titration. SPA was characterized by Fourier transform infrared (FTIR), and scanning electron microscope (SEM) was used to adsorption of malachite green (MG) and methyl violet (MV) 2B. The back titration result showed that mass ratio of SB-PA 0.5:5 and reaction time 6 hours as the optimum conditions with the number of carboxylic groups of 359.36 x 10-2 mmol g-1. The FTIR result showed that SPA has a characteristic peak of carboxylic groups and SPA has the bigger pore size than SB showed by SEM. The optimum adsorption condition of MG with the value 121.94 mg g-1 was achieved at 20 mg SPA, pH 4 for 11 hours. The optimum adsorption condition of MV 2B with the value 71.17 mg g-1 was achieved at 30 mg SPA, pH 5 for 7 hours. The adsorption kinetics followed a pseudo-second-order with the rate constants for MG and MV 2B 1.21 x 10-2 and 0.68 x 10-2 hour-1, respectively. The adsorption behavior fit quite well with Freundlich model with adsorptions energy for MG and MV 2B 32.18 and 32.39 kJ mol-1, respectively.

Keywords:   sugarcane bagasse, phthalate anhydride, adsorption, malachite green, methyl violet 2B 

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Bharali, D., and Deka, R. C., 2017, A solution of ternary CuMgAl layered double hydroxide, Colloids and Surf., A, 525: 64–76. 

Bonetto, L.R., Ferrarini, F., De Marco, C., Crespo, J.S., Guégan, R., and Giovanela, M., 2015, Removal of methyl violet 2B dye from aqueous solution using a magnetic composite as an adsorbent. J. Water Proc., Eng., 6: 11–20.

Chen, C.H., Chang, C.F., and Liu, S.M., 2010, Partial degradation mechanisms of malachite green and methyl violet B by Shewanella decolorationis NTOU1 under anaerobic conditions. J. Hazard. Mater. 177: 281–289.

Chiou, M. S., and Chuang, G. S., 2006, Competitive adsorption of dye metanil yellow and RB15 in acid solutions on chemichally crosslinked chitosan beads. Chemosphere, 62: 731740.

Culp, S. J., Mellick, P. W., Trotter, R. W., Greenlees, K. J., Kodell, R. L., and Beland, F. A., 2006, Carcinogenicity of malachite green chloride and leucomalachite green in B6C3F1 mice and F344 rats. Food Chem. Toxicol., 44: 1204–1212

Fayazi, M., and Azizian, S., 2016, Catalytic degradation of methyl violet without light irradiation using nanostructured CuS. J. Mol. Liq., 224: 763–767. 

Hameed, B.H., 2008, Equilibrium and kinetic studies of methyl violet sorption by agricultural waste. J. Hazard. Mater. 154: 204–212.

Ho, Y. S., and McKay, G., 1999, Pseudo-second order model for sorption processes. Process Biochem., 34: 451–465.

Jalil, A. A., Triwahyono, S., Yaakob, M. R., Azmi, Z. Z. A., Sapawe, N., Kamarudin, N. H. N.,

Setiabudi, H. D., Jaafar, N. F., Sidik, S. M., Sadam, S. H., Hameed, B. H., 2010, Utilization of bivalve shell-treated Zea mays I. (maize) husk leaf as a low-cost biosorbent for enhanced adsorption of malachite green, Bioresour., Technol., 120: 218224.

Kristianto, Dwi, 2016, Pembuatan Manik Kompleks Polielektrolit Kitosan Pektin sebagai Adsorben Zat Warna Malahite Green dan Metil Violet 2B, Tesis, Jurusan Kimia, Universitas Gadjah Mada, Yogyakarta. 

Kuppusamy, S., Venkateswarlu, K., Thavamani, P., Lee, Y. B., Naidu, R., and Megharaj, M., 2017, Quercus robur acorn peel as a novel coagulating adsorbent for cationic dye removal from aquatic ecosystems. Ecol. Eng., 101: 3–8.

Kalavathy, M.H., and Miranda, L.R., 2010, Comparison of copper adsorption from aqueous solution using modified and unmodified Hevea brasiliensis saw dust, Desalination, 255: 165– 174.

Luo, X. P., Fu, S. Y., Du, Y. M., Guo, J. Z., and Li, B., 2017, Adsorption of methylene blue and malachite green from aqueous solution by sulfonic acid group modified MIL-101. Microporous and Mesoporous Mater., 237: 268– 274.

Musyoka, S. M., Mittal, H., Mishra, S. B., and Ngila, J. C., 2014, Effect of functionalization on the adsorption capacity of cellulose for the removal of methyl violet. Inter. J. Biol. Macromol., 65: 389–397.

Pavia, D., Lampman, G., Kriz, G., Vyvyan, J., 2014, Introduction to Spectroscopy, Cengange Learning.

Rajabi, M., Mirza, B., Mahanpoor, K., Mirjalili, M., Najafi, F., Moradi, O., and Gupta, V. K., 2016, Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: Determination of equilibrium and kinetics parameters. J. Ind. Eng., 34: 130–138.

Ramos, S. N. do C., Xavier, A. L. P., Teodoro, F. S., Gil, L. F., and Gurgel, L. V. A., 2016, Removal of cobalt(II), copper(II), and nickel(II) ions from  aqueous solutions using phthalatefunctionalized sugarcane bagasse: Mono- and multicomponent adsorption in batch mode. Ind.l Crops. Prod., 79: 116–130. 

Ramos, S. N. do C., Xavier, A. L. P., Teodoro, F. S., Elias, M. M. C., Gonçalves, F. J., Gil, L. F., and Gurgel, L. V. A., 2015, Modeling mono- and multi-component adsorption of cobalt(II), copper(II), and nickel(II) metal ions from aqueous solution onto a new carboxylated sugarcane bagasse. Part I: Batch adsorption study. Ind. Crops. Prod., 74: 357–371. 

Robinson, T., McMullan, G., Marchant, R., Nigam, P., 2001, Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative, Bioresour., Technol., 77: 247-255.

Reis, D. L., G. T., Robaina, N. F., Pacheco, W. F., and Cassella, R. J, 2011, Separation of Malachite Green and Methyl Green cationic dyes from the aqueous medium by adsorption on Amberlite XAD-2 and XAD-4 resins using sodium dodecylsulfate as a carrier. J. Chem. Eng., 171: 532–540. 

Santosa, S. J., Jumina, dan Sri, S., 2003, Sintesis Membran Biourai Selulosa Asetat dan Adsorben Super Karboksimetilselulosa dari Selulosa Ampas Tebu Limbah Pabrik Gula, Jurusan Kimia, Universitas Gadjah Mada, Yogyakarta.

Sewu, D. D., Boakye, P., and Woo, S. H., 2016, Highly efficient adsorption of cationic dye by biochar produced with Korean cabbage waste. Bioresour. Technol., 224: 206–213.

Suryadi, B. U., 2016, Aplikasi Lignoselulosa Sulfonat Ampas Tebu untuk Adsorpsi Zat Warna Tekstil Kationik Basic Violet 10, J. Kimia dan Pendidikan Kimia, 1: 11-19.

Sun, R.-C., and Yuan, T.-Q., 2010, Chapter 1 – Introduction. In Cereal Straw as a Resource for Sustainable Biomaterials and Biofuels, pp. 1–7.

Tuny, M. T., 2013, Adsorpsi Desorpsi Biru metilen pada Membran Kompleks Polielektrolit (PEC) Kitosan-Pektin, Tesis, Jurusan Kimia, Universitas Gadjah Mada, Yogyakarta.

Tian, G., Wang, W., Kang, Y., and Wang, A., 2016, Ammonium sulfide-assisted hydrothermal activation of palygorskite for enhanced adsorption of methyl violet. J. Env. Sci., 41: 33– 43.

Wu, W., Luo, Z.-D., Wang, J., and Liu, J., 2017, Photocatalytic degradation of methyl violet and rhodamine B based on an extremely stable metal-organic framework decorated with carboxylate groups. Inorg. Chem. Commun., 36: 605-611. 

Zhang, F., Ma, B., Jiang, X., and Ji, Y., 2016, Dual function magnetic hydroxyapatite nanopowder for removal of malachite green and Congo red from aqueous solution. Powder Technol., 302: 207–214. 

Zhou, Y., Min, Y., Qiao, H., Huang, Q., Wang, E., and Ma, T., 2015, Improved removal of malachite green from aqueous solution using chemically modified cellulose by anhydride. Inter. J. Biol. Macromol., 74: 271–277.  

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