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ADSORPTION OF PHENOL POLLUTANTS FROM AQUEOUS SOLUTION USING Ca-BENTONITE/CHITOSAN COMPOSITE

https://doi.org/10.22146/jml.18747

Poedji Loekitowati Hariani(1*), Fatma Fatma(2), Fahma Riyanti(3), Hesti Ratnasari(4)

(1) Department of Chemistry, Faculty of Mathematics and Science, Sriwijaya University Jalan Raya Palembang-Prabumulih km. 32, Indralaya, Ogan Ilir, 30662.
(2) Department of Chemistry, Faculty of Mathematics and Science, Sriwijaya University Jalan Raya Palembang-Prabumulih km. 32, Indralaya, Ogan Ilir, 30662.
(3) Department of Chemistry, Faculty of Mathematics and Science, Sriwijaya University Jalan Raya Palembang-Prabumulih km. 32, Indralaya, Ogan Ilir, 30662.
(4) Department of Chemistry, Faculty of Mathematics and Science, Sriwijaya University Jalan Raya Palembang-Prabumulih km. 32, Indralaya, Ogan Ilir, 30662.
(*) Corresponding Author

Abstract


Phenolic compounds areorganic pollutants that are toxic and carcinogenic.The presence of phenol in the environmentcan be adverse to humanand the environmentalsystem. One methodthat iseffective toreduce thephenolisadsorption. In this study, the adsorption of phenol in aqueous solution using Ca-bentonite/chitosan composite was investigated. Chitosan is the deacetylation product of chitin from shrimp waste. Characterization of Ca-bentonite/chitosan composite was done by using Fourier Transform Infrared (FTIR) and Scanning Electron Microscopy-Energy Dispersive X Ray Spectroscopy (SEM-EDX). Batch adsorption studies were performed to evaluate the effects of some parameters such as initial concentration of phenol, composite weight, pH and contact time. The results showed that FTIR spectra of Ca-bentonite/chitosan composite presented the characteristic of peak of Ca-bentonite and chitosan that confirmed the successful synthesis of composite. The SEM-EDX characterizationresultsshowedCa-bentonite surfacecoverage by chitosanand the presence ofcarbonandnitrogenelementsinCa-bentonite/chitosancompositeindicated that chitosan had bonded with bentonite. The optimum condition of adsorption of Ca-bentonite/chitosan to phenol was obtained at 125 mg.L-1 of concentration in which the weight of composite was 1.0 g, the pH of solution was 7, the contact time was 30 minutes, and the capacity of adsorption was 12.496 mg.g-1.

Keywords


adsorption; bentonite; chitosan; composite; phenol; pollutant; adsorpsi; bentonit; fenol; kitosan; komposit; polutan



References

Anonim, 1995. Baku Mutu Limbah Cair Bagi Industri. Keputusan Menteri Negara Lingkungan Hidup No.51/MENLH/10/1995.

Bhatnagar, A., and Minocha, A.K., 2009. Adsorptive Removal of 2,4-Dichlorophenol from Water Utilizing Punica Granatum Peel Waste and Stabilization With Cement. Journal Hazard Material, 168(2-3):1111-1117.

Cardenas, S.A., Tzasari, G.V., Guillermo, O.R., Ma. Del Socorro, l.C., and Brenda, G.P., 2005. Adsorption of Phenol and Dichlorophenols from Aqueous Solutions by Porous Clay Heterostructure J. Mex. Chem. Soc., 49(3):287-291.

Dai, J., Ren, F.L., and Tao, C.H., 2012. Adsorption of Cr(VI) and Speciation of Cr(VI) and Cr(III) in Aqueous Solution Using Chemically Modified Chitosan. Int. J.. Environ. Res. Public Health, 9:1757-1770.

Futalan, C.M., Kan, C.C., Maria, L.P.D., Chelo, P., Shien, K.J., and Wan, M.W., 2011. Nickel Removal from Aqueous Solution in Fixed Bed Using Chitosan-Coated Bentonite. Sustainable Environ. Res., 21(6):361-367.

Girish, C.R., and Ramachandra, M., 2012. Adsorption of Phenol from Wastewater Using Locally Available Adsorbents. Journal of Environmental Research and Development, 6(3A):763-772.

Hashem, F.S., 2012. Adsorption of Methylene Blue from Aqueous Solutions Using Fe3O4/ Bentonite Nanocomposite. Hydrology Current Research, 3(5):1-6.

Hariani, P.L., and Fatma, 2007. Karakterisasi Adsorpsi Cd(II) Pada Adsorben Kitosan Hasil Preparasi Udang Galah (Cryphios rosenbergii). Jurnal Ilmiah MIPA, 10(1):23-29.

Hitzky, E.R., Margarita, D., and Pilar, A., 2005. Functional Hybrid Organic-Inorganic Nanostructured. BioNanohybrid Material, 2nd Nanospain, Barcelona.

Knop, A., and Pilato, L.A., 1985. Phenoloic Resins-Chemistry, Applications and Peformance. Springer-Verlag. Berlin Heildenberg.

Ling, J.M., Meng, X.G., HU, C.W., and Du, J., 2009. Adsorption of Phenol, p-Chlorophenol, and p-Nitrophenol onto Functional Chitosan. Bioresource Technology, 100:1168-1173.

Lynam, M.M., Kilduff, J.E., and Weber, W.J., 1995. Adsorption of p-Nitrophenol from Dilute Aqueous Solution. J. Chem. Educ., 72:80-85.

Mahajan, S.P., 1994. Pollution Control in Processes Industries. Tata Mc.Graw Hill, New Delhi.

Michalowicz, J., and Duda, W., 2004. Chlorophenola and Their Derivatives in Water of the Drainage of the Dzierzazna River. State and Anthropogenic Changes of the Quality of Waters in Poland. Ed 3. Hydrological Commitee of Polish Geograph. Soc. University of Lodz. Poland.

Michalowicz, J., and Duda, W., 2007. Phenols-Source and Toxicity. Review. Polish J. Environ. Stud., 16(3):347-362.

Monvisade, P., and Siriphannon, P., 2009. Chitosan Intercalated Montmorilonite: Preparation, Characterization and Cationic Dye Adsorption. Applied Clay Science, 42(3-4):427-431.

No, H.K., Lee, S.H., Park, N.Y., and Meyers, S.P., 2003. Comparison of Phsicochemichal Binding and Antibacterial Properties of Chitosan Prepared Without and With Deproteinization Process. J. Agric. Food Chem., 51:2-10.

Permatasari, A., Wiwi, S., and Irnawati, W., 2010. Uji Kinerja Adsorben Kitosan-Bentonit Terhadap Logam Berat dan Diazinon Secara Simultan. Jurnal Sains dan Teknologi Kimia, 1(2):121-134.

Rahmi. 2007. Adsorpsi Fenol Pada Membran Komposit Kitosan Berikatan Silang. Jurnal Rekayasa Kimia dan Lingkungan, 6(1):28-34.

Rocha, L.L., De Aguiar, C.R., Cavalcante, R.M., Do Nascimento, R.F., Martins, S.C., Santaela, S.T., and Melo, V.M., 2007. Isolation and Characterization of Phenol Degrading Yeasts from An Oil Refinery Wastewater in Brazil. Mycopathologia, 164(4):183-188.

Saravakumar, K., and Kumar, A., 2013. Removal of Phenol from Aqueous Solution by Adsorption Using Zeolite. Academic Journal, 8(23):2985-2965.

Senturk, H.B., Ozdes, D., Gundogdu, A., Duran, C., and Soylak, M., 2009. Removal of Phenol from Aqueous Solutions by Adsorption onto Organomodified Tirebolu Bentonite: Equilibrium, Kinetic and Thermodynamic Study. Journal of Hazardouz Materials, 172:353-362.

Shen, Y.H., 2002. Removal of Phenol from Water by Adsorption-Flocculation Using Organobentonite. Water Research, 36:1107-1114.

Srihari, V., and Das, A., 2009. Adsorption of Phenol from Aqueous Media by an Agro Waste (Hemidesmus Indicus) Based Activated Carbon. Applied Ecology and Environmetal Research, 7(1):13-23.

Swart, M., Verhagen, F., Field, J., and Wijnberg, J., 1998. Trichlorinated Phenols for Hypholoma Epongatum. Phytochem., 49:203-210.

Tran, H.V., Tran, L.D., and Nguyen, T.N., 2010. Preparation of Chitosan/Magnetite Composite Beads and Their Application for Removal of Pb(II) and Ni(II) from Aqueous Solution. Materials Science and Engineering Chemistry, 30:304-310.

Uddin, M.T., Islam, M.S., and Abedin, M.Z., 2007. Adsorption of Phenol from Aqueous Solution by Water Hyacinth Ash. ARPN J. Eng. & App. Sci., 2(2):11-17.

Zhang, Y., Wang, D., Liu, B., Gao, X., Xu, W., Liang, P., and Xu, Y., 2013, Adsorption of Fluoride from Aqueous Solutions Using Low-Cost Bentonite/Chitosan Beads. Am. J. Anal. Chem., 4:48-53.



DOI: https://doi.org/10.22146/jml.18747

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