A Study on Synthesis and Testing of Polyols Using Soybean Oil and Castor Oil

https://doi.org/10.22146/ajche.49729

Shahzad Maqsood Khan(1*), Nafisa Gull(2), Muhammad Yaseen Akram(3), Hakim Ali Haider(4), Muhammad Yasir Akram(5), Muhammad Imran(6), Muhammad Taqi Zahid Butt(7), Tahir Jamil(8)

(1) 
(2) 
(3) 
(4) 
(5) 
(6) 
(7) 
(8) 
(*) Corresponding Author

Abstract


The feasibility of methods of trans-esterification reactions for the preparation of polyols from unsaturated soybean oil and castor oil have shown in this study. The polyol products formed from soybean oil has primary alcohol functional group. For castor oil polyol, hydroxyl group of any chain of triglyceride is replaced by chlorine. Thus the polyol formed has two hydroxyl (-OH) groups. Polyol is identified from hydroxyl functional group using Fourier Transform Infrared Spectroscopy (FTIR), and characterized by acid value. It is seen that the synthesized polyols are useful in the treatment of processes, using polyols for the production of polyurethanes, and also manipulated to synthesize polyurethane with required properties.

Keywords


Polyol, Soybean polyol, Castor oil, FTIR

Full Text:

PDF


References

1. ASTM D464 Standard Test Method for Determination Saponification Number of Naval Stores Products Including Tall Oil and Other Related Products.
2. ASTM D5768-02 Standard Test Method for Determination of Iodine Value of Tall
Oil Fatty Acids.
3. ASTM D4662 Standard Test Method for Determination of Acid value.
4. ASHIDA, K. 2007. Polyurethane and Related Foams, Raton London Newyork, Taylor & Francis.
5. BAYER, O. 1947a. Angewandte Chemie, A. 59.
6. BAYER, O. 1947b. Modern Plastics. 24.
7. DETROIT. 1998. Proceedings of an International Symposium on 60 Years of Polyurethanes. In, USA.
8. EL-TAYEB, N. S. M. 2008. A study on the potential of sugarcane fibers/polyester composite for tribological applications. Wear, 265, 223-235.
9. FEI, Y., ZHIPING, L., PAUL, C., YUHUAN, L., XIANGYANG, L., ROGER, R. 2008. Atmospheric Pressure Liquefaction of Dried Distillers Grains (DDG) and Making Polyurethane Foams from Liquefied DDG. Appl. Biochem. Biotechnol., 148, 235-243.

10. GUO, A., CHO, Y. J., PETROVIC, Z. S. 2000. Structure and properties of halogenated and nonhalogenated soy- based polyols. J. Polym. Sci.: Part A: Polym. Chem., 38, 3900-3910.

11. GUO, A., DEMYDOV, D., ZHANG, W., PETROVIC, Z. S. 2002. Polyols and Polyurethanes from hydro formylation of soybean oil. J. Polym. Environ., 10, 49- 52.
12. HATICE, M., AND MICHAEL, A. R. M. 2010. Castor oil as a renewable resource for the chemical industry. European Journal od Lipid Science and Technology, 112, 10-30.
13. JHON, J., BHATTACHARYA, M., TURNER, R. B. 2002. Characterization of polyurethane foams from soybean oil. J. Appl. Polym. Sci., 86, 3097-3107.
14. KHOE, T., OTEY, F., FRANKEL, E. 1972. Rigid urethane foams from hydroxy urethylated linseed oil and polyol esters. J. Am. Oil. Chem. Soc., 49, 615-
618.
15. LONESCU, M. 2005. Chemistry andTechnology of Polyols for Polyurethanes, Shawbury, Shrewsbury, Shropshire, SY4 4NR, United Kingdom, Rapra Technology Limited.
16. MAXIME, E., MYRIAM, D., REMI, A., SYLVAIN, C., BERNARD, B. 2012. From Vegetable Oils to Polyurethanes: Synthetic Routes to Polyols and Main Industrial Products. Polymer Reviews,
52, 38-79.
17. MIHAIL, I., ZORAN, S. P., XIANMEI, W. 2007. Ethoxylated Soybean Polyols for Polyurethanes. J. Polym. Environ., 15, 237-243.

18. MYRIAM, D., SYLVAIN, C., VINCENT, L., REMI, A., BERNARD, B. 2011. Synthesis of Biobased Polyols by ThiolEne Coupling from Vegetable Oils. Macromolecules, 44, 2489-2500.
19. PHUONG, T., DANIEL, G., RAMANI, N. 2005. Ozone-Mediated Polyol Synthesis from Soybean Oil. J10972 in JAOCS, 82, 653-659.
20. SIMONE, C. G., MARCO, F. F., ANNELISE, E. G. 2007. Determination of the Hydroxyl Value of Soybean Polyol by Attenuated Total reflectance/Fourier Transform Infrared Spectroscopy. J. Amer. Oil. Chem. Soc., 84, 503-508.

21. STEFAN, O. 2010. Synthesis and Properties of Polyurethane Elastomers with Castor Oil as Crosslinker. J. Am. Oil. Chem. Soc., 87, 313-320.
22. SURESH, S. N., XIAOHUA, K., LAZIZ, B., PETER, S. 2007. Physical Properties of Polyurethanes Produced from Polyols from Seed Oils: II. Foams. J. Amer. Oil. Chem. Soc., 84, 65-72.
23. SZYCHER, M. 1999. Isocynate Chemistry, New York.
24. XIAOHUA, K., GUOGUANG, L., HONG, Q., JONATHAN, M. C. 2013. Preparation and characterization of high-solid polyurethane coating systems based on vegetable oil derived polyols. Progress in Organic Coatings, 76, 1151-1160.



DOI: https://doi.org/10.22146/ajche.49729

Article Metrics

Abstract views : 2814 | views : 3179

Refbacks

  • There are currently no refbacks.


ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.