Photocatalytic Hydrogen Production over Ni/La-NaTaO3 Nanoparticles from NaCl-water Solution in the Presence of Glucose as Electron Donor

https://doi.org/10.22146/ajche.49553

Husni Husin(1*), Komala Pontas(2), Yunardi Yunardi(3), Adi Salamun(4), Pocut Nurul Alam(5), Fikri Hasfita(6)

(1) Department of Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia; Graduate Program in Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia
(2) Department of Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia; Graduate Program in Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia
(3) Department of Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia; Graduate Program in Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia
(4) Department of Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia
(5) Department of Chemical Engineering, Syiah Kuala University, Darussalam, 23111, Banda Aceh, Indonesia
(6) Department of Chemical Engineering, Malikussaleh University, Lhoekseumawe, 24300, Aceh Utara, Indonesia
(*) Corresponding Author

Abstract


Nanoparticles La-NaTaO3 photocatalyst has been synthesized via a sol-gel route. A Ni
nanoparticle (NPs) as a cocatalyst is loaded on La-NaTaO3 by a simple impregnation method.
The products are characterized by X-ray diffraction (XRD), scanning electron microscope
(SEM), a high-resolution transmission electron microscope (HRTEM) and X-ray photoelectron
spectroscopy (XPS). X-ray diffraction of the La-NaTaO3 samples shows perovskite-type
crystalline orthorhombic structure. Small particulate solids of La-NaTaO3 (30-250 nm) are
observed by SEM measurement. The nickel particles are detected from HRTEM images is
around 4-8 nm. The hydrogen evolution over La-NaTaO3 with NaCl is much higher than that
without NaCl. The photoactivity of La-NaTaO3 is enhanced when Ni is loaded on the surface
of La-NaTaO3. The optimum loading amount of nickel is found to be 0.3 wt.% for La-NaTaO3,
and it is more effective for H2 production from NaCl-water solution in the presence glucose.
It is revealed that the loaded Ni can interact with each other and cooperate on improving the
photocatalytic activity. In the case of glucose as an electron donor, the activity of
photocatalytic hydrogen generation over Ni/La-NaTaO3 increases dramatically. NaCl and
glucose can promote markedly the photocatalytic hydrogen evolution. The Ni/La-NaTaO3
nanoparticles system appears to be a promising candidate, which is very important to practical
applications, including the production of H2 from NaCl-water solution in the presence of
glucose.


Keywords


La-doped sodium tantalum oxide; Nickel; Photocatalyst; Glucose; Hydrogen energy

Full Text:

PDF


References

  1. Chen, W.T., Chan, A., Sun-Waterhouse, D., Moriga, T., Idriss, H., Waterhouse, G.I.N., 2015. "Ni/TiO2: A promising low- cost photocatalytic system for solar H2 production from ethanol–water mixtures", Journal of Catalysis,326, 43- 53.
  2. Chen, W.T., Chan, A., Sun-Waterhouse, D., Moriga, T., Idriss, H., Waterhouse, G.I.N., 2015. "Ni/TiO2: A promising low- cost photocatalytic system for solar H2 production from ethanol–water mixtures", Journal of Catalysis,326, 43- 53.
  3. Chowdhury, P., Gomaa, H., Ray, A.K., 2015. "Sacrificial hydrogen generation from aqueous triethanolamine with Eosin Y-sensitized Pt/TiO2 photocatalyst in UV, visible and solar light irradiation", Chemosphere, 121, 54-61.
  4. Fu, X., Wang, X., Leung, D.Y.C., Xue, W., Ding, Z., Huang, H., Fu, X., 2010. "Photocatalytic reforming of glucose over La doped alkali tantalate photocatalysts for H2 production", Catalysis Communications, 12, 184-187.
  5. Husin, H., Adisalamun, Sy, Y., Asnawi, T.M., Hasfita, F., 2017. "Pt nanoparticle on La0.02Na0.98TaO3 catalyst for hydrogen evolution from glycerol aqueous solution", AIP Conference Proceedings, AIP Publishing, p. 030073.
  6. Husin, H., Mahidin, M., Yunardi, Y., Hafita, F., 2015. "Visible Light Driven Photocatalytic Hydrogen Evolution by Lanthanum and Carbon-co-Doped NaTaO3 Photocatalyst", Key Engineering Materials, 659. 231-236.
  7. Husin, H., Mahidin, M., Zuhra, Z., Hafita, F., 2014a. "H2 evolution on Lanthanum and Carbon co-doped NaTaO3 Photocatalyst", Bulletin of Chemical Reaction Engineering & Catalysis, 9, 81- 86.
  8. Husin, H., Nien, S.W., Jern, P.C., Yue, L.J., John, R., Chiang, Y.S., Tsung, C.W., Shuenn, S.H., Joe, H.B., 2013. "Pd/NiO core/shell nanoparticles on La 0.02 Na 0.98 TaO3 catalyst for hydrogen evolution from water and aqueous methanol solution" International Journal of Hydrogen Energy,38, 13529-13540.
  9. Husin, H., Pontas, K., Sy, Y., Syawaliah, S., Saisa, S., 2014b. "Synthesis of Nanocrystalline of Lanthanum Doped NaTaO3 and Photocatalytic Activity for Hydrogen Production", Journal of Engineering and Technological Sciences,46, 318-327.
  10. Husin, H., Su, W.N., Chen, H.M., Pan, C.J., Chang, S.H., Rick, J., Chuang, W.T., Sheu, H.S., Hwang, B.J., 2011. "Photocatalytic hydrogen production on nickel-loaded LaxNa1-xTaO3 prepared by hydrogen peroxide-water based process", Green Chem. 13, 1745 -1754.
  11. Ji, S.M., Jun, H., Jang, J.S., Son, H.C., Borse, P.H., Lee, J.S., 2007. "Photocatalytic hydrogen production from natural seawater", Journal of Photochemistry and Photobiology A: Chemistry,189, 141-144.
  12. Kato, H., Asakura, K., Kudo, A., 2003. "Highly Efficient Water Splitting into H2 and O2 over Lanthanum-Doped NaTaO3 Photocatalysts with High Crystallinity and Surface Nanostructure", Journal of the American Chemical Society,125, 3082-3089.
  13. Kudo, A., Miseki, Y., 2009. "Heterogeneous photocatalyst materials for water splitting" Chemical Society Reviews,38, 253-278.
  14. Li, Y., He, F., Peng, S., Gao, D., Lu, G., Li, S., 2011. "Effects of electrolyte NaCl on photocatalytic hydrogen evolution in the presence of electron donors over Pt/TiO2", Journal of Molecular Catalysis A: Chemical, 341, 71-76.
  15. Li, Y., Lin, S., Peng, S., Lu, G., Li, S., 2013. "Modification of ZnS1−x−0.5yOx(OH)y– ZnO photocatalyst with NiS for enhanced visible-light-driven hydrogen generation from seawater", International Journal of Hydrogen Energy,38, 15976-15984.
  16. Maeda, K., Masuda, H., Domen, K., 2009. "Effect of electrolyte addition on activity of (Ga1-xZnx)(N1-xOx) photocatalyst for overall water splitting under visible light" Catalysis Today,147, 173-178.
  17. Muradov, N.Z., Veziroğlu, T.N., 2008. “Green path from fossil-based to hydrogen economy: An overview of carbon-neutral technologies”, International Journal of Hydrogen Energy,33, 6804-6839.
  18. Shinde, S.S., Bhosale, C.H., Rajpure, K.Y., 2011. "Photocatalytic activity of sea water using TiO2 catalyst under solar light”, Journal of Photochemistry and Photobiology B: Biology, 103, 111-117.
  19. Strataki, N., Antoniadou, M., Dracopoulos, V., Lianos, P., 2010. "Visible-light photocatalytic hydrogen production from ethanol-water mixtures using a Pt-CdS-TiO2 photocatalyst”, Catalysis Today 151, 53- 57.
  20. Yan, S.C., Wang, Z.Q., Li, Z.S., Zou, Z.G., 2009. "Photocatalytic activities for water splitting of La-doped-NaTaO3 fabricated by microwave synthesis”, Solid State Ionics, 180, 1539-1542.
  21. Yang, X.J., Wang, S., Sun, H.M., Wang, X.B., Lian, J.S., 2015. "Preparation and photocatalytic performance of Cu- doped TiO2 nanoparticles”, Transactions of Nonferrous Metals Society of China, 25, 504-509.



DOI: https://doi.org/10.22146/ajche.49553

Article Metrics

Abstract views : 3068 | views : 2302

Refbacks

  • There are currently no refbacks.


ASEAN Journal of Chemical Engineering  (print ISSN 1655-4418; online ISSN 2655-5409) is published by Chemical Engineering Department, Faculty of Engineering, Universitas Gadjah Mada.